表五、杯莧甾酮(Cyasterone)的氫、碳化學位移(DMSO-d6)a
position
|
|
dH (600 MHz)
|
|
dC (150 MHz)
|
|
1
|
|
1.26 (t, 12.6), 1.58 (m)
|
|
36.6
|
|
2
|
|
3.58 (m)
|
|
66.8
|
|
3
|
|
3.75 (m)
|
|
66.6
|
|
4
|
|
1.45 (t, 3.6), 1.58 (m)
|
|
31.5
|
|
5
|
|
2.18 (m)
|
|
50.1
|
|
6
|
|
|
|
202.7
|
|
7
|
|
5.62 (s)
|
|
120.5
|
|
8
|
|
|
|
165.1
|
|
9
|
|
2.99 (t, 8.4)
|
|
33.1
|
|
10
|
|
|
|
37.6
|
|
11
|
|
1.47 (m), 1.64 (m)
|
|
20.1
|
|
12
|
|
1.70 (m), 2.02 (m)
|
|
30.8
|
|
13
|
|
|
|
46.9
|
|
14
|
|
|
|
82.9
|
|
15
|
|
1.50 (m), 1.81 (m)
|
|
30.4
|
|
16
|
|
1.87 (m)
|
|
20.2
|
|
17
|
|
2.20 (m)
|
|
48.6
|
|
18
|
|
0.83 (s)
|
|
23.9
|
|
19
|
|
0.76 (s)
|
|
17.2
|
|
20
|
|
|
|
75.7
|
|
21
|
|
1.06 (s)
|
|
20.6
|
|
22
|
|
3.32 (m)
|
|
73.3
|
|
23
|
|
1.36 (m), 1.52 (m)
|
|
33.2
|
|
24
|
|
1.87 (m)
|
|
47.8
|
|
25
|
|
2.43 (m)
|
|
41.5
|
|
26
|
|
|
|
178.7
|
|
27
|
|
1.16 (d, 7.2)
|
|
15.1
|
|
28
|
|
4.15 (m)
|
|
79.3
|
|
29
|
|
1.31 (d, 6.0)
|
|
19.1
|
|
2-OH
|
|
4.41 (d, 6.0)
|
|
|
|
3-OH
|
|
4.34 (d, 3.0)
|
|
|
|
14-OH
|
|
4.63 (s)
|
|
|
|
20-OH
|
|
3.74 (s)
|
|
|
|
22-OH
|
|
4.37 (d, 4.8)
|
|
|
|
a(Multiplicity, J in Hz) in ppm. |